Utilization of oyster shell waste (crassostrea gigas) as a source of calcium in hydroxyapatite synthesis

Irhamni Irhamni, Eka Juliana, Eka Juliana, Zulfalina Zulfalina, Zulfalina Zulfalina, Fauzi Fauzi, Fauzi Fauzi, Zulkarnain Jalil, Zulkarnain Jalil

Abstract


Biomaterials are materials that interact with living tissues for the purpose of treating and replacing tissues either temporarily or permanently. Biomaterials can be developed from hydroxyapatite-based materials. The source of calcium for the manufacture of hydroxyapatite is obtained from oyster shell waste (Crassostrea gigas) from the waters of Alue Naga Banda Aceh. The purpose of this study was to examine the opportunity to utilize oyster shell waste as a source of calcium for hydroxyapatite synthesis. The hydroxyapatite synthesis process was carried out by calcining oyster shells at a temperature of 10000C for 5 hours to obtain calcium oxide (CaO) content. Then, the CaO powder was reacted with phosphoric acid (H3PO4) to obtain hydroxyapatite compound (Ca10(PO4)6(OH)2) and then sintered at 900C for 2 hours. Analysis of CaO and hydroxyapatite phases was carried out through XRD (X-Ray Diffraction) characterization results. Surface morphology and element content were obtained from SEM-EDS characterization. Based on the analysis, CaO and hydroxyapatite phases have been successfully formed and the surface morphology of hydroxyapatite crystal structure is not clearly visible because of the formation of agglomeration. Based on the elemental content test, the ideal Ca/P ratio has not been obtained. Based on the results of the research, oyster shell waste (Crassostrea gigas) from the waters of Alue Naga, in Syiah Kuala District, Banda Aceh City has the opportunity to be utilized as a source of calcium in hydroxyapatite synthesis and can be developed as a biomaterial.


Keywords


Fisika Material

Full Text:

PDF

References


Affandi, A, Z. (2015). Sintesis Hidroksiapatit dari Cangkang Kerang Darah (Andara granosa) dengan proses Hidrotermal Variasi Rasio mol Ca/P dan Suhu Sintesis. Jom FTEKNIK, Vol.2 No.1.

Agung, R., Elizabeth, B. E., & Martono, Y. 2(020). Biokramik Hidroksiapatit (HAp) Berbahan Dasar Cangkang Tiram Anodonta Nuttaliana dari Danau puso. Jurnal Ipb.ac id/index php / Jhhpi, 1110-39x.

Gergely, G., Wéber, F., Lukacs, I., Toth, A. L. Horvath, Z. E., Mihaly, J. & Balazsi, C. (2019). Preparation and Characterization of Hydroxyapatite from Eggshell. Ceramics International 36 (2010) 803-806. Elsevier.

Handayani, L & Syaputra, F. (2017). Isolasi dan Karakterisasi Nanokalsium dari cangkang Tiram (Crassostrea gigas). Jurnal Ipb.ac id/index php / Jhhpi. Vol.20 No.3.

Iqhbal, W. P, Prabowo,T. A, dan Wahyudi, B. (2020). Kinetika Reaksi Sintesis Hidroksiapatit dari Cangkang Kerang Darah (Andara granosa) dengan Metode presipitasi. Seminar nasional teknik kimia soebardjo. XVI 2020.

Nontji A.,. Laut Nusantara. Djambatan. Jakarta. 1993

Park, J., &Lakes, R.S. 2007. Biomaterials: An Introduction. Springer: USA. 2007

Rini, Purwo. 2015. Sintesis Hidroksiapatit Dari Cangkang Kerang Kepah (Polymesoda Erosa) Dengan Variasi Waktu Pengadukan, Jurnal. ISSN 23021077.

Sari, R.N., Fransiska, D., Dewi, F.R., dan Sinurat, E. (2022). Karakteristik Sediaan Hidroksiapatit dari Cangkang Kerang Simping (Amusium pleuronectes) dengan Perlakuan Suhu dan Waktu Sintesis. JPB Kelautan dan Perikanan Vol. 17 No. 1 Tahun 2022: 31-42

Salamanu, S.A., (2017). IdentifikasiJenis Tiram Dan Keragamannya Di Daerah Intertidal Desa Haria Kecamatan Saparua Kabupaten Maluku Tengah. Jurnal Penelitian Sains Dan Pendidikan.Vol 6. No. 2. (2017) 171-175

Salsabila, I. 2018. Pengaruh variasi temperatur sintering dan variasi komposisi air dalam suspensi terhadap karakteristik lapisan hidroksiapatit (ukuran kristal, derajat kristalinitas, dan ketebalan) berbasis tulang sapi untuk aplikasi coating dental implant. Skripsi: Universitas Syiah Kuala, Banda Aceh.

Sawettree. R, Kumpapan. P, & Wanjonoi. 2014. Synthesis of Hydroxyapatite from Oyster Shell via Precipitation. Energy Procedia. 56 (2014) 112 – 117.

Smallman, R. E., & Bishop, R. J. Metalurgi Fisik Modern dan Rekayasa Material Edisi Keenam. Erlangga, Jakarta. 2020

Wardani, N.S., Fadli, A., dan Irdoni. (2015). Sintesis Hidroksiapatit Dari Cangkang Telur Dengan Metode Presipitasi. JOM FT, Universitas Riau

Yusuf, U.K., Firda, Y.S,. Ishak, P., dan Vicky, J. Hidroksiapatit berbahan dasar biogenic. Yogyakarta: Gadjah Mada University Press. 2019




DOI: https://doi.org/10.52626/jg.v7i2.357

Refbacks

  • There are currently no refbacks.


Published by: Geuthèë Institute

St. Teknik II,  Reumpet, Krueng Barona Jaya sub-district (23370), Aceh Besar District, Aceh Province, Indonesia.

E-mail: jurnalgeuthee@gmail.com; jurnal@geutheeinstitute.com

Website: http://geutheeinstitute.com/

 

ISSN (Online): 2614–6096

Lisensi Creative Commons
The published content of this journal is licensed under a Lisensi Creative Commons Atribusi 4.0 Internasional.